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51.
The changes in the phytoplankton absorption properties during a diurnal cycle were investigated at one station located in the north-western area of the Alborán Sea. The experiment was performed in spring when the water column was strongly stratified. This hydrological situation permitted the establishment of a deep chlorophyll a (chl a) fluorescence maximum (DFM) which was located on average close to the lower limit of the mixed layer and the nutricline. The relative abundance of pico-phytoplankton (estimated as its contribution to the total chl a) was higher in the surface, however, micro-phytoplankton dominated the community at the DFM level. Chl a specific absorption coefficient (a*(λ)) also varied with optical depth, with a* (the spectrally average specific absorption coefficient) decreasing by 30% at the DFM depth with respect to the surface. A significant negative correlation between the contribution of the micro-phytoplankton to the total chl a and a* was obtained indicating that a* reduction was due to changes in the packaging effect. Below the euphotic layer, a* increased three-fold with respect to the DFM, which agrees with the expected accumulation of accessory pigments relative to chl a as an acclimation response to the low available irradiance. The most conspicuous change during the diurnal cycle was produced in the euphotic layer where the chl a concentration decreased significantly in the afternoon (from a mean concentration of 1.1 μg L−1 to 0.7 μg L−1) and increased at dusk when it averaged 1.4 μg L−1. In addition, a* and the blue-to-red absorption band ratio increased in the afternoon. These results suggest that a*(λ) diurnal variability was due to increase in photo-protective and accessory pigments relative to chl a. The variation ranges of a*(λ) at 675 and 440 nm (the absorption peaks in the red and blue spectral bands, respectively) in the euphotic layer were 0.01–0.04 and 0.02–0.10 m2 mg−1 chl a, respectively. Approximately 30% out of this variability can be attributed to the diurnal cycle. This factor should therefore be taken into account in refining primary production models based on phytoplankton light absorption.  相似文献   
52.
Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater.  相似文献   
53.
Abstract. The stomach contents of poor cod, Trisopterus minutus capelanus (Lacepède), were taken at monthly intervals off the eastern coast of the Gulf of Valencia (Spain). A total of 1276 were analyzed to determine diet according to fish size and season. The basic food consists of crustaceans (Mysidacea and Decapoda) and teleosts. Feeding habits varied with size: decapods and fishes were more abundant in the stomachs of larger specimens. Little seasonal variation in food habits was recorded.  相似文献   
54.
The enzymatic activity of alkaline phosphatase (APA) was studied in the transition zone between the African upwelling system and the open ocean waters of the Canary Islands region. This region is recurrently dominated by the presence of upwelling filaments that may transport nutrient-enriched waters out into the open ocean before nutrients become exhausted by plankton. Turnover rates by APA were generally low in the whole region, but detectable in all the measurements carried out. On average, turnover rates were higher in the upwelling stations, and APA in those waters seemed to be mainly generated by heterotrophic bacteria to supply easily assimilable organic C. APA outside the upwelling area showed an inverse hyperbolic relationship with increasing phosphate, suggesting the presence of both constitutive and Pi-inducible APA. In these offshore waters, a threshold of 0.1 μM of phosphate could be defined for the regulatory function of Pi on APA. Thus, APA in nutrient-poor waters seemed to be induced to compensate for Pi-deficiency. Turnover rates in the filaments showed basal (probably constitutive) levels, whereas they increased in the surrounding waters, where phosphate concentration presumably did not satisfy plankton P-demands. The fertilising effect of the filaments and associated cyclonic eddies extended to at least 175 km offshore, where basal alkaline phosphatase activities were still found. The magnitude of this effect depends probably on the intensity of upwelling events and the degree of recirculation of filament water back to the coastal jet.  相似文献   
55.
The Besòs prodelta, located around a highly populated area, receives the discharge of the Besòs River, one of the most contaminated rivers discharging into the Mediterranean sea. The record of heavy metals accumulated in this prodelta is studied to assess the sedimentary behaviour and the history of the anthropogenic heavy metals in the area.

dated sediments have allowed the identification of the sedimentation patterns and the elaboration of dated heavy metals and cenospheres profiles, which reflected the evolution of the anthropogenic impact in this marine environment. Sediments accumulated during the 18th and 19th centuries were already affected by a moderate heavy metal contamination. This contamination increased drastically in the sediments accumulated during the last decades. This data is well correlated with the increase in industrialisation, population and energy consumption in the Besòs drainage basin during the last century.  相似文献   
56.
Abstract

Intra and inter-annual variations in the sea ice thickness are highly sensitive indicators of climatic variations undergoing in the earth’s atmosphere and oceans. This paper describes the method of estimating sea ice thickness using radar waveforms data acquired by SARAL/Altika mission during its drifting orbit phase from July 2016 onwards yielding spatially dense data coverage. Based on statistical analysis of return echoes, classification of the surface has been carried out in three different types, viz. floe, lead and mixed. Time delay correction methods were suitably selected and implemented to make corrections in altimetric range measurements and thereby freeboard. By assuming hydrostatic equilibrium, freeboard data were converted into sea ice thickness. Results show that sea ice thickness varies from 4 to 5?m near ice shelves and 1 to 2.5?m in the marginal sea ice regions. Freeboard and sea ice thickness estimates were also validated using NASA’s Operation Ice Bridge (OIB) datasets. Freeboard measurements show very high correlation (0.97) having RMSE of 0.13. Overestimation of approximately 1–2?m observed in the sea ice thickness, which could be attributed to distance between AltiKa footprint and OIB locations. Moreover, sensitivity analysis shows that snow depth and snow density over sea ice play crucial role in the estimation of sea ice thickness.  相似文献   
57.
The muricid gastropod Bolinus brandaris exhibited imposex, a phenomenon linked to the use of organotin biocides. Several stages of imposex development (1-5) could be distinguished and were documented with SEM-photographs for the first time in this species. Additional alterations of the genital tract in females (blocked vulva preventing copulation and deposition of egg capsules) and males (excrecences on the penis and vas deferens) were shown. Imposex intensity on the Catalan coast was very high. The frequency of imposex off Barcelona and Vilanova i la Geltrú was 100%, with all females showing stage 4. Imposex frequency off Sant Carles de la Ràpita was 99.7% and the VDS index scored 3.9. Despite regulations of TBT-containing antifouling paints in Spain since 1990, the present study revealed that frequency and intensity of imposex have increased on the Catalan coast, at least since 1997. However, at present, imposex does not apparently affect the population dynamics of B. brandaris in the studied area, since no serious consequences on female reproduction (only one case of female sterilization) were detected. Gonadal activity and oogenesis were not suppressed or supplanted by spermatogenesis. Sex ratios were not male-biased. Possible sources of organotin biocides are examined.  相似文献   
58.
The Maracaibo Estuary is of particular interest because of its location in the tropics, its large size (over 12,000 km2), the economic importance of its underlying hydrocarbon deposits and its increasing rate of pollution. Sediments from this estuary were studied in order to characterise their capacity to adsorb and desorb phosphorus. Considerable variability in capacity for phosphate sorption was found among the seventeen samples studied. This variability can be attributed first to the differences among the samples in total P content and, secondly, to their differences in free iron content. Also, it appears that P retention contributes to the control of P concentration in the water and therefore the sediments serve as a buffer in controlling P eutrophication in the estuary.  相似文献   
59.
Abstract. Eight sandy beaches were seasonally sampled along the coast of Chile, from ca. 21 to 42° S (about 3000 km) to study the relationship between community structure of the intertidal macroinfauna and beach characteristics. Sediment samples (0.1 m2, 30 cm deep) were collected (July – September 1998 and December 1998 – January 1999) with plastic cylinders at 15 equally spaced levels along three replicated transects extending from above the drift line to the swash zone. The sediment was sieved through a 1 mm mesh and the organisms collected stored in 5 % formalin. To define beach types, Dean's parameter (Ω) was calculated from wave heights and periods, and fall velocity of sand particles from the swash zone. Crustaceans (mainly peracarids) were the most diverse group with 14 species, followed by polychaetes with 5 species. The talitrid amphipod Orchestoidea tuberculata , the cirolanid isopods Excirolana braziliensis and E. hirsuticauda and the anomuran decapod Emerita analoga were the most widely distributed and common species. Regression analyses between species richness, abundance and biomass of the whole macroinfauna versus sediment characteristics, beach face slopes and morphodynamic beach states showed no significant relationships. Thus, macroinfaunal community characteristics did not increase linearly from lower intermediate to higher intermediate or dissipative beach states as had been found before in Chile or in other coasts. A comparative analysis with data from sandy beaches of other world regions showed that the number of species inhabiting Chilean sandy beaches was generally lower, whereas total population abundances were generally higher compared with values reported elsewhere.  相似文献   
60.
A bottom longline fishery operated in the EEZ of New Caledonia from 1988 to 1991. Fishing focused on five seamounts with summits at depths ranging from 500 to 750 m. The target species was alfonsino, Beryx splendens. As the soundings available from marine charts were not detailed enough, the fishing masters had to make their own charts in order to set the gear in the right location. A series of 11 scientific cruises devoted to a research program on alfonsino was launched in late 1991. During the first scientific cruises, several days were spent mapping the seabed to improve the existing knowledge of the topography of three seamounts by coupling the EDO echosounder depth measurements to the GPS positions. As this procedure is slow, it is applicable to limited areas or, if a wider grid is used, to large zones to locate major structures such as ridges and seamounts. The emergence of the multibeam echosounder has greatly improved seabed mapping performance. This tool seems to fit the requirement of exploratory deep-bottom fishing particularly well, as it covers large areas while providing details of the bottom. The EM 12 was used to obtain bathymetry and imagery of the SE portion of the EEZ of New Caledonia, covering an approximate area of 70,000 km2 in two weeks. For depths ranging from 500 to 4,500 m, the results were impressive. They confirmed the known major features and provided greater topographical detail, revealing fine unknown structures. They also provided information on the type of substratum, information which might influence the fishing strategy. Finally, they made it possible to obtain an accurate estimate of the exploitable area which in turn led to new stock estimates.  相似文献   
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